The speed of a molecule in a uniform gas at equilibrium is a random variable whose probability density function is given by

` $$ \begin{aligned} f(x) &= ax^2 e^{-bx^2}, x\geq 0 \end{aligned} $$ `

where `$b = m/2kT$`

and $k$, $T$, and $m$ denote, respectively, Boltzmann's constant, the absolute temperature of the gas, and the mass of the molecule. Evaluate $a$ in terms of $b$.

#### Solution

As given $f(x)$ is a probability density function, we have

` $$ \begin{aligned} &\int_0^\infty f(x) \; dx = 1\\ &\Rightarrow \int_0^\infty ax^2 e^{-bx^2} \; dx = 1\\ &\Rightarrow a \int_0^\infty x^{2*(3/2) -1} e^{-bx^2} \; dx = 1\\ &\Rightarrow a \frac{\Gamma(3/2)}{2b^{3/2}} = 1\\ & \quad \quad \text{using } \int_0^\infty x^{2n-1}e^{-ax^2}\; dx =\frac{\Gamma(n)}{2a^n}\\ &\Rightarrow a \Gamma(3/2) =2b^{3/2}\\ &\Rightarrow a \frac{1}{2}\Gamma(1/2) =2b^{3/2}\\ &\Rightarrow a \frac{1}{2}\sqrt{\pi} =2b^{3/2}\\ &\Rightarrow a =\frac{4b^{3/2}}{\sqrt{\pi}} \end{aligned} $$ `

Using `$\Gamma(n)=(n-1)\Gamma(n-1)$`

and `$\Gamma(1/2) =\sqrt{\pi}$`

.

#### Further Reading

- Statistics
- Descriptive Statistics
- Probability Theory
- Probability Distribution
- Hypothesis Testing
- Confidence interval
- Sample size determination
- Non-parametric Tests
- Correlation Regression
- Statistics Calculators